If Windows PE + Defraggler can't do it, try http://www.mydefrag.com/
IIRC it can be programmed to run at boot, being able to move around MFT and related data.
Wound up, can't sleep, can't do anything right, little honey / Oh, since I set my eyes on you. / I tell you the truth. I can't get it right / Get it right / Since I met you...
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